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Termed ZIF1 to 12) have been synthesized as crystals by copolymerization of either Zn(II) (ZIF1 to 4, 6 to 8, and 10 to 11) or Co(II) (ZIF9 and 12) with imidazolatetype links The ZIF crystal structures are based on the nets of seven distinct aluminosilicate zeolites tetrahedral Si(Al) and the bridging O are replaced with.

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